Reaxis® C220 - Monobutyltin Tris-(2-ethylhexanoate)
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REAXIS® C220 (Monobutyltin Tris-(2-Ethylhexanoate)) is a liquid organotin homogenous catalyst that is used primarily as an esterification catalyst. Alternatively, but less commonly, REAXIS® C220 can be used as a polyurethane catalyst. Monobutyltin Tris-(2-Ethylhexanoate) is a monobutyltin-based organotin that is lower in toxicity compared to dibutyl-based organotins. Of the commonly used tin catalysts in esterification, REAXIS® C220 is the only liquid catalyst available. Other commonly used esterification catalysts include REAXIS® C248 (Dibutyltin Oxide) and inorganic tin products including REAXIS® C129 (Stannous Octoate), REAXIS® C160 (Stannous Oxalate), REAXIS® C162 (Stannous Chloride), and REAXIS® C188 (Stannous Oxide).
Technical Information
- Product Category Organotin
- Chemical Name Monobutyltin Tris-(2-ethylhexanoate)
- CAS Number 23850-94-4
Typical Specifications
| Parameter | Range |
|---|---|
| Tin Content (%) | 18.8 Min |
| Viscosity (cP @ 20°C) | 180 Max |
| Color (Gardner Number) | 3 Max |
| Acid Number (mgKOH/g) | 255 - 285 |
| Chloride (%) | 1.0 Max |
International Regulatory Listings
- TSCA (US) Yes
- DSL (Canada) Yes
- AICS (Australia) Yes
- KECI (South Korea) Yes
- IECSC (China) Yes
- ENCS (Japan) Yes
- TCSI (Taiwan) Yes
- NZloC (New Zealand) Yes
- PICCS (The Philippines) Yes
Applications
REAXIS® C220 is primarily used as an esterification catalyst, specifically for both monomeric and polymeric saturated and unsaturated esters. End-use applications include personal care, lubricants, coatings and plastics. REAXIS® C220 is ideal for applications where end-product toxicity is of critical concern given its monoalkyl makeup. Monobutyltin Tris-(2-Ethylhexanoate) can also be used as a polyurethane catalyst in select formulations.
Reactivity
Like most organotins used in esterifications, the key attributes of Monobutyltin Tris-(2-Ethylhexanoate) are its high-temperature stability, low color as supplied, good reactivity as evidenced by low acid number endpoints, and minimal reactivity-derived color effects on the final product. Compared to titanium catalysts, Monobutyltin Tris-(2-Ethylhexanoate) also has improved hydrolytic stability, which is especially important during the initial stages of the esterification reaction. As tin concentration is more correlated with reactivity in esterifications, the use of Monobutyltin Tris-(2-Ethylhexanoate) must be increased when compared to higher tin products such as REAXIS® C248 (Dibutyltin Oxide) and REAXIS® C160 (Stannous Oxalate). But, as these effects are formulation/raw material dependent, the negative effects of lower tin content on reactivity can be overcome, either when a liquid catalyst will compatibilize more efficiently with alcohol/acid raw materials used, or there is related ligand compatibility.
Package & Storage
- 44 lb (20 kg) plastic pail
- 440 lb (200 kg) steel drum
REAXIS® C220 should be stored in the original packaging at moderate temperatures and kept from freezing. The container should be closed tightly after each use to maximize shelf life. Characteristic of most Sn (IV) organotins, the primary cause of instability would be hydrolysis. Hydrolysis results in the formation of tin oxide insolubles leading to deactivation of REAXIS® C220.
Safety and Handling
Hazard Classification (US SDS)
| Section | Hazard Class | Category | Hazard Statement |
|---|---|---|---|
| A.2 | skin corrosion/irritation | 2 | H315 |
| A.3 | serious eye damage/eye irritation | 2 | H319 |
Hazard Pictograms (US SDS)
Transportation Information (US SDS)
| DOT | IMDG | ICAO | Environment Hazard | |
|---|---|---|---|---|
| UN Number | not assigned | not assigned | not assigned | non-environmentally hazardous acc. to the dangerous goods regulations |
| UN Proper Shipping Name | not relevant | not relevant | not relevant | |
| Transport Class | none | none | none | |
| Packing Group | not assigned | not assigned | not assigned | |
Primary Composition Substance(s)
- Butyltris[(2-ethyl-1-oxohexyl)oxy]stannane
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This information is provided to the best of our knowledge but without obligation. Reaxis is not liable for any incorrect or missing information. This data sheet becomes invalid upon publication of a new version. Please contact us for the latest version.
